nano silica phosphoric acid: an efficient catalyst for the one- pot synthesis of 1, 2, 4, 5-tetrasubstituted imidazoles
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abstract
two simple protocols for the synthesis of 1, 2, 4, 5- tetrasubstitutedimidazoles using nano-spa as a reusable, eco- friendly, inexpensive, and efficient catalyst are reported. short reaction times, high yields, scale-up and easy workup are the advantages of these protocols.
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Nano Silica Phosphoric Acid: An Efficient Catalyst for the One- Pot Synthesis of 1, 2, 4, 5-Tetrasubstituted Imidazoles
Two simple protocols for the synthesis of 1, 2, 4, 5- tetrasubstitutedimidazoles using nano-SPA as a reusable, eco- friendly, inexpensive, and efficient catalyst are reported. Short reaction times, high yields, scale-up and easy workup are the advantages of these protocols.
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full textKaolin-SO3H as an efficient catalyst for one-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles
Kaolin-SO3H as a new solid acid is prepared via reaction of kaolin and chlorosulfonic acid. This natural based catalyst is very inexpensive and easy available. Imidazoles are an important class of heterocycles being the core fragment of different natural products and biological systems such as anti-allergic, anti-inflammatory, analgesic, antifungal, antimycotic, antibiotic, antiulcerative, anti...
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چکیده ندارد.
Nano-Silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones (thiones) under solvent-free or sonication conditions
Two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1H)-ones (thiones) using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.
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Journal title:
journal of nanostructuresPublisher: university of kashan
ISSN 2251-7871
volume 2
issue 1 2012
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